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Dicyclohepta[cd,gh]pentalen, ein neues Pyren-Isomeres

✍ Scribed by Dr. Henning Reel; Prof. Dr. Emanuel Vogel


Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
299 KB
Volume
84
Category
Article
ISSN
0044-8249

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Dicyclohepta[cd,gh]pentalene—A New Pyren
✍ Dr. Henning Reel; Prof. Dr. Emanuel Vogel 📂 Article 📅 1972 🏛 John Wiley and Sons 🌐 English ⚖ 261 KB

152-155"C, which is recyclized to (3a) by phosgene in the presence of a tertiary amine. 3,4-Dichloroaniline reacts with (3a) even at ca. 20"C, giving the monothiotriuret (6a), m.p. 163°C. (3a) can be prepared from (la) and phenoxycarbonyl isocyanate in boiling toluene even in absence of a tertiary b