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Dicyano-Functionalized MCM-41-Supported Palladium Complex as An Efficient Catalyst for Allylation of Aldehydes and Ketones

✍ Scribed by Hong Zhao; Ming-Zhong Cai

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 62 KB
Volume: 24
Category: Article
ISSN: 0256-7660
DOI: 10.1002/cjoc.200690313

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✦ Synopsis

Abstract

Dicyano‐functionalized MCM‐41‐supported palladium complex was prepared from dicyano‐functionalized MCM‐41 and palladium chloride. This complex exhibited high catalytic activity in the allylation of aldehydes and ketones with allylic chlorides in the presence of SnCl~2~. This polymeric palladium complex can be recovered and reused without noticeable loss of activity.

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