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Dichloro­(N,N′-dibenzyl­ethane-1,2-diamine-κ2N,N)zinc(II)

✍ Scribed by Liu, Y.-F. ;Xia, H.-T. ;Yang, S.-P. ;Wang, D.-Q.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
432 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [ZnCl 2 (C 16 H 20 N 2 )], the Zn cation is coordinated by two Cl anions and two N atoms of N,N 0dibenzylethane-1,2-diamine in a distorted tetrahedral geometry. The molecules are linked into dimers by N-HÁ Á Á Cl and C-HÁ Á ÁCl hydrogen bonds; neighboring dimers are linked into a sheet by C-HÁ Á Á Cl hydrogen bonds.

📜 SIMILAR VOLUMES

[N,N′-Dimethyl-N′′-(2-pyridylmethyl­ene)
[N,N′-Dimethyl-N′′-(2-pyridylmethyl­ene)ethane-1,2-diamine]dithio­cyanato­zinc(II)
✍ Chen, Guang ;Bai, Zhi-Ping ;Qu, Sheng-Ju 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 119 KB

The title compound, [Zn(NCS) 2 (C 10 H 15 N 3 )], is a mononuclear zinc(II) complex. The molecule is isostructural with the analogous copper(II) compound [Yue, Xu, Shi & Feng (2005). Acta Cryst. E61, m693-m694]. The Zn atom exhibits a square pyramidal geometry.