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Dichlorocarbene, free or complexed? Relative reactivities of free CCl2

โœ Scribed by Skell, Philip S.; Cholod, M. S.


Book ID
127226991
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
445 KB
Volume
91
Category
Article
ISSN
0002-7863

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Cisand trans-buten-2-yl free radicals are shown to react with D2S in metathetical steps: Relative formation rates of monodeuteriated butenes in D2S -2 -C,Hs mixtures were measured at low extent of reaction in the experimental range: 20-200 torr 2 -C4Hs, 0-41-torr D2S and 717-817 K. In these pressur