metal-organic papers m1222 Sevim Tu È rktekin et al. [CoCl 2 (C 11 H 14 N 2 O) 2 ] Acta Cryst. (2004). E60, m1220±m1222
Dichlorobis(1H-benzimidazole-κN3)cobalt(II)
✍ Scribed by Yoe-Reyes, Francisco-Javier ;Bernès, Sylvain ;Barba-Behrens, Noráh
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 194 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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The title compound, [CoCl~2~(C~11~H~11~N~3~O~2~)~2~], was synthesized from 1-(but-2-enyl)-5-nitrobenzimidazole and cobalt dichloride in ethanol. The Co^II^ atom has a distorted tetrahedral geometry, coordinated by two Cl atoms and two N atoms. The molecule is located on a twofold rotation axis, whic
The title compound, [NiCl 2 (C 11 H 14 N 2 O) 2 ], was synthesized from 1-(2-ethoxyethyl)benzimidazole and nickel dichloride in ethanol and is isostructural with its cobalt analogue. It shows a distorted tetrahedral geometry about Ni II , involving two Cl atoms and two benzimidazole N atoms. The cry
The Co II atom in the mononuclear title complex, [Co(C 8 H 5 -Cl 2 O 3 ) 2 (C 3 H 4 N 2 ) 2 (H 2 O) 2 ], lies on an inversion center. The Co II atom has an octahedral coordination, involving two carboxylate O atoms of two monodentate 2,4-dichlorophenoxyacetate ligands, two N atoms of imidazole ligan