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Dichloro­{2-[(2-isopropyl­amino­ethyl­imino)meth­yl]-4-nitrophenolato}zinc(II)

✍ Scribed by Wang, Shou-Xing

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
222 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [ZnCl~2~(C~12~H~17~N~3~O~3~)], a mononuclear Schiff base zinc(II) complex, the Zn atom is tetrahedrally coordinated by one imine N atom and one phenolate O-atom of the Schiff base ligand and by two terminal chloride anions. In the crystal structure, symmetry-related molecules are linked through intermolecular N—H...Cl, N—H...O and C—H...Cl hydrogen bonds, forming chains running parallel to the b axis.

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Dichloro­{2,4-dichloro-6-[2-(isopropyl­ammonio)ethyl­imino­meth­yl]phenolato}zinc(II)
✍ Hu, Yang-Jian 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 122 KB

Single-crystal X-ray study T = 298 K Mean (C-C) = 0.005 A R factor = 0.044 wR factor = 0.100 Data-to-parameter ratio = 21.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.