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Dicarbonylrhodium(I) complexes of benzoylpyridine ligands: Synthesis, reactivity and catalytic carbonylation reaction

โœ Scribed by Bibek Jyoti Borah; Biswajit Deb; Podma Pollov Sarmah; Dipak Kumar Dutta


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
263 KB
Volume
319
Category
Article
ISSN
1381-1169

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Dicarbonylrhodium(I) complexes of functi
โœ Nandini Kumari; Bhaskar Joyti Sarmah; Dipak Kumar Dutta ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 249 KB

Reactions of dimeric complex [Rh(CO) 2 Cl] 2 (1) with pyridine ester ligands methyl picolinate (a), methyl nicotinate (b), methyl isonicotinate (c), ethyl picolinate (d), ethyl nicotinate (e) and ethyl isonicotinate (f) in the 1:2 molar ratio afford the complexes of the type [Rh(CO) 2 ClL] (1a-f). T