Diboraethene compounds as ligands in metal complexes: XIV. Synthesis and crystal structure of bis(η5-3,4-diethyl-2,5-dimethyl-1,2,5-thiadiborolene)monocarbonyliron
✍ Scribed by Joseph Edwin; Walter Siebert; Carl Krüger
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 486 KB
- Volume
- 282
- Category
- Article
- ISSN
- 0022-328X
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The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ĹnBH 4
## Abstract The structures of [Pd(__η__^3^‐C~3~H~5~)(Hpz^R2^)~2~](BF~4~) (Hpz^R2^=Hpz^bp2^=3,5‐bis(4‐butoxyphenyl)‐1__H__‐pyrazole, 1; Hpz^R2^=Hpz^NO2^=3,5‐dimethyl‐4‐nitro‐1__H__‐pyrazole=Hdmnpz, 2) and [Ag(Hpz^R2^)~2~](A) (Hpz^R2^=Hpz^bp2^, A=$\rm{ BF\_4^ -}$, 3; Hpz^R2^=Hpz^NO2^, A=$\rm{ CF\_3 S