## Abstract The mass spectrometric behaviour of a series of 6,6βdisubstituted dibenzo(__d,f__)(1,3)dioxepine derivatives have been studied. The fragmentation patterns were described and discussed in detail with the aid of labelled compounds, accurate mass measurements and collisionally induced diss
Dibenzo[d,f][1,3] dioxepine derivatives: A review
β Scribed by Hai-Quan Zhang; Cheng-Bo Zhang
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2011
- Tongue
- English
- Weight
- 637 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0022-152X
- DOI
- 10.1002/jhet.253
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β¦ Synopsis
Abstract
This review presents a survey of synthetic methods and reaction mechanism of the dibenzo[d,f][1,3] dioxepine derivatives. Furthermore, the influence of the substituent groups in 6,6β²βposition of dibenzo[d,f][1,3] dioxepine on their conformation is explored. The functional dibenzo[d,f][1,3] dioxepine synthetically versatiles substrate, as they can be used for synthesis of a large variety of Οβconjugated oligomer and polymer containing heterocyclic compounds, such as dibromination dibenzo[d,f][1,3] dioxepine derivative as a raw material of synthesis for organic semiconductor polymers. The synthetic and fluorescent property of Οβconjugated polymers basic on dibenzo[d,f][1,3] dioxepine also is explored. J. Heterocyclic Chem., (2012).
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