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Dibenzo[d,f][1,3] dioxepine derivatives: A review

✍ Scribed by Hai-Quan Zhang; Cheng-Bo Zhang


Publisher
Journal of Heterocyclic Chemistry
Year
2011
Tongue
English
Weight
637 KB
Volume
49
Category
Article
ISSN
0022-152X

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✦ Synopsis


Abstract

This review presents a survey of synthetic methods and reaction mechanism of the dibenzo[d,f][1,3] dioxepine derivatives. Furthermore, the influence of the substituent groups in 6,6′‐position of dibenzo[d,f][1,3] dioxepine on their conformation is explored. The functional dibenzo[d,f][1,3] dioxepine synthetically versatiles substrate, as they can be used for synthesis of a large variety of π‐conjugated oligomer and polymer containing heterocyclic compounds, such as dibromination dibenzo[d,f][1,3] dioxepine derivative as a raw material of synthesis for organic semiconductor polymers. The synthetic and fluorescent property of π‐conjugated polymers basic on dibenzo[d,f][1,3] dioxepine also is explored. J. Heterocyclic Chem., (2012).


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## Abstract The mass spectrometric behaviour of a series of 6,6‐disubstituted dibenzo(__d,f__)(1,3)dioxepine derivatives have been studied. The fragmentation patterns were described and discussed in detail with the aid of labelled compounds, accurate mass measurements and collisionally induced diss