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Diazoaldehyde Chemistry. Part 3. Synthesis of 4-acyl-1H-1,2,3-triazole derivatives

✍ Scribed by Özkan Sezer; Kadir Dabak; Ahmet Akar; Olcay Anaç

Publisher
John Wiley and Sons
Year
1996
Tongue
German
Weight
353 KB
Volume
79
Category
Article
ISSN
0018-019X

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Synthesis of novel 1,3-substituted 1H-[1
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## By means of regioselective S-alkylation of 1H-1,2,4-triazole-3-thiol (1), a series of S-substituted derivatives 2a-j were synthesized. In certain conditions, the reaction of 2 with arylsulfochlorides, arylisocyanates, and quaternary ammonium salts of azines corresponding compounds were obtained

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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## Abstract Ribosylated 1,2,3‐triazole **__4__** and **__5__** were synthesized in moderate yields by the reaction of aroyl‐substituted heterocyclic ketene aminals **__1__** or **__2__** with 2,3,5‐tri‐O‐benzoyl‐β‐D‐ribofuranosyl azide (**__3__**). Their structures were determined by elemental anal