Single-crystal X-ray study T = 273 K Mean '(C±C) = 0.005 A Ê R factor = 0.059 wR factor = 0.138 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Diazidobis(2,2′-bipyridine)zinc(II) monohydrate
✍ Scribed by Jian, Fangfang ;Li, Chunlei ;Sun, Pingping ;Xiao, Hailian
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 167 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.025 wR factor = 0.071 Data-to-parameter ratio = 14.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.012 A Ê R factor = 0.081 wR factor = 0.169 Data-to-parameter ratio = 12.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the centrosymmetric title compound, [Zn(C 15 H 13 N 2 O 2 ) 2 -(C 5 H 5 N) 2 ], the Zn atom is chelated by the O and N atoms of two bidentate ligands. The coordination geometry of the central Zn atom is octahedral. The crystal packing is stabilized by intermolecular CÐHÁ Á ÁO interactions.
## Abstract The N~4~ donor ligand, Me~2~bpzb^2−^ and a pyridine molecule are coordinated to the Zinc(II) so that the coordination geometry closely resembles a square‐pyramidal environment with a nitrogen atom of the pyridine ligand occupying the apical position. Copyright © 2003 John Wiley & Sons,