Diastereospecific Tandem Prins Cyclisation/Rearrangement Reactions for the Desymmetrisation of Cyclohexa-1,4-dienes

✍ Scribed by Mark C. Elliott; Nahed N. E. El Sayed; James S. Paine

• Publisher: John Wiley and Sons
• Year: 2007
• Tongue: English
• Weight: 275 KB
• Volume: 2007
• Category: Article
• ISSN: 1434-193X
• DOI: 10.1002/ejoc.200600928

✦ Synopsis

Abstract

The Prins cyclisation has been used for the first time to desymmetrise a 1,4‐diene. Products derived from both normal Prins and rearrangement pathways were obtained, all with complete stereocontrol. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)