Diastereospecific synthesis of β-heterosubstituted alcohols from 1,2-diols via 1,3,2λ5-dioxaphospholanes
✍ Scribed by Henri-Jean Cristau; Michel Carteron; Alain Fruchier; Jean-Luc Pirat
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 124 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1387-1609
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## Abstract Easily accessible 2‐benzoylamino‐3,3‐dichloroacrylonitrile, when treated successively with primary amines, phosphorus pentachloride, sulfur dioxide, and various N‐ or S‐nucleophiles, furnishes the corresponding derivatives of 1,2‐dihydro‐2λ^5^‐[1,3]oxazolo[5,4‐__d__][1,3,2]diazaphosphin
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