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Diastereoselectivity in uncatalyzed intramolecular CH insertion by an alkylidene carbene

✍ Scribed by Douglass F. Taber; Robert P. Meagley

Book ID
103402222
Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
126 KB
Volume
35
Category
Article
ISSN
0040-4039

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📜 SIMILAR VOLUMES

Improved chemoselectivity in intramolecu
Improved chemoselectivity in intramolecular alkylidene carbene CH insertion
✍ Douglass F. Taber; Thomas E. Christos 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 149 KB

The alkylidene carbene generated by chloromethylenation / or-elimination of 1 proceeds with a high degree of selectivity for methoxy C-H insertion over methine insertion, to give 2. The carbene generated with trimethylsilyldiazomethane results in an approximately 1:1 mixture of 2 and 3.

ChemInform Abstract: Improved Chemoselec
ChemInform Abstract: Improved Chemoselectivity in Intramolecular Alkylidene Carbene C-H Insertion.
✍ D. F. TABER; T. E. CHRISTOS 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 27 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v