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DiastereoselectiveDiels-AlderReaction of 2-Thienyl and 2-Furyl Substituted 3-Propenethioamides with Electron Deficient Dienophiles

✍ Scribed by Krystyna Bogdanowicz-Szwed; Artur Budzowski


Book ID
106213312
Publisher
Springer Vienna
Year
2004
Tongue
English
Weight
441 KB
Volume
135
Category
Article
ISSN
0026-9247

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Reaction of 2-substituted-4-oxo-4H-pyrid
✍ Masashi Shirai; Hidekazu Kuwabara; Satoshi Matsumoto; Hidetoshi Yamamoto; Akikaz πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 282 KB

A facile oxime-nitrone isomerization through the 1,2-hydrogen shift in 4-oxo-4H-pyrido[1,2-a]pyrimidine-3-carbaldehyde oximes is discussed. The resultant NH-nitrones are trapped by maleimides to afford intermolecular cycloadducts. The reaction of the oximes with electron-deficient acetylenes undergo