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Diastereoselective synthesis of α-substituted β-amidophosphonates

✍ Scribed by Géraldine Castelot-Deliencourt; Xavier Pannecoucke; Jean-Charles Quirion

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 75 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)02145-6

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✦ Synopsis

A simple and general asymmetric synthesis of b-amidophosphonates is described. The method involves the highly selective addition (up to 95% d.e.) of diethyl phosphite to various chiral a,b-unsaturated carboxylic amides derived from chiral aminoalcohols.

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