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Diastereoselective synthesis of N-acetyl-D,L-acosamine and N-benzoyl-D,L-ristosamine

✍ Scribed by Masahiro Hiroma; Takeo Shigemoto; Yutaka Yamozaki; Shô Itô

Book ID: 104222503
Publisher: Elsevier Science
Year: 1985
Tongue: French
Weight: 243 KB
Volume: 26
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)89312-0

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✦ Synopsis

N-Acyl derivatives of D,L-acosamine and D,L-ristosamine were synthesized with high stereoselectivity utilizing -7 -intramolecular Michael addition of Y-and 6-carbamoyloxy-a, P-unsaturated esters. Recently we have found prominent 1,2-and 1,3-asymmetric induction in the intramolecular Michael

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