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Diastereoselective synthesis of chiral β-amino-α-hydroxy-H-phosphinates through hydrophosphinylation of α-amino aldehydes

✍ Scribed by Takehiro Yamagishi; Kenji Suemune; Tsutomu Yokomatsu; Shiroshi Shibuya

Book ID: 104230974
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 98 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)00911-x

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✦ Synopsis

A stereodivergent synthesis of b-amino-a-hydroxy-H-phosphinates was achieved by ALB-catalyzed hydrophosphinylation of N,N-dibenzyl-a-amino aldehydes tuning the chirality of the catalyst.

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