Diastereoselective Synthesis of 4,5-Dihydrofurans by Iodoenolcyclization of 2-Allyl-1,3-dicarbonyl Compounds.
✍ Scribed by Roberto Antonioletti; Savina Malancona; Paolo Bovicelli
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 179 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Radical cyclizations of fluorinated 1,3‐dicarbonyl compounds with dienes mediated by Mn(OAc)~3~ afforded 4,5‐dihydrofurans containing difluoroacetyl, trifluoroacetyl, or heptafluorobutanoyl groups in good‐to‐excellent yields. Additionally, 2‐(difluoromethyl)‐4,5‐dihydrofurans and a 4,7‐
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