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Diastereoselective Syntheses of Deoxydysibetaine, Dysibetaine, and Its 4-Epimer

✍ Scribed by Langlois, Nicole; Le Nguyen, Bao K.

Book ID
125539984
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
152 KB
Volume
69
Category
Article
ISSN
0022-3263

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✍ Yuichi Kobayashi; Michitaka Matsuumi πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 77 KB

Stereoselective synthesis of 12-oxo-PDA starting with (1R,3S)-cyclopenten-1,3-diol monoacetate is accomplished. Key transformations are copper-catalyzed installation of the C(1)-C(8) chain onto the cyclopentene ring and construction of the C(14)-C(18) chain. Similarly, 13-epi-12-oxo-PDA was synthesi