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Diastereoselective Silacyclopropanations of Functionalized Chiral Alkenes

✍ Scribed by Driver, Tom G.; Franz, Annaliese K.; Woerpel, K. A.


Book ID
127172099
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
47 KB
Volume
124
Category
Article
ISSN
0002-7863

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Diastereoselective [3+2]-photocycloaddit
✍ Yasuo Kubo; Masahiro Yoshioka; Satoshi Nakajima; Isamu Inamura πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 216 KB

3+2]-Photocycloaddition of di-(-)-menthyl, di-(-)-8-phenylmenthyl, and di-(-)-bornyl 1,4naphthalenedicarboxylates to alkenes, such as isobutene, styrene, and ~-methylstyrene, proceeded with diastereoselectivity, up to 62% diastereomeric excess (de), largely depending on the concavity of the auxiliar