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Diastereoselective Self-Assembly of Double- and Triple-Stranded Helicates from a d -Isomannide Derivative

✍ Scribed by Kiehne, U.; Lützen, A.

Book ID
126825808
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
134 KB
Volume
9
Category
Article
ISSN
1523-7060

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## Abstract Unsymmetrical substituted bidentate benzimidazol‐2‐ylpyridine ligands L2 and L3 react with [Ru(dmso)~4~Cl~2~] in ethanol to give statistical 1:3 mixtures of __fac__‐[Ru(L__i__)~3~]^2+^ and __mer__‐[Ru(L__i__)~3~]^2+^ (__i__=2, 3; Δ__G__⊖~isomerisation~=−2.7 kJ mol^−1^). In more polar so