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Diastereoselective propargylation of sugar aldehydes. New synthesis of 6-deoxyheptoses

โœ Scribed by Zbigniew Pakulski; Aleksander Zamojski


Book ID
108374554
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
809 KB
Volume
53
Category
Article
ISSN
0040-4020

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ChemInform Abstract: Diastereoselective
โœ Z. PAKULSKI; A. ZAMOJSKI ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 35 KB

Diastereoselective Propargylation of Sugar Aldehydes. New Synthesis of 6-Deoxyheptoses. -Treatment of sugar aldehydes with propargyl bromide in the presence of Zn is found to give homopropargylic alcohols in good yields. Products with D-manno, D-gluco, as well as D-altro configurations are obtained