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Diastereoselective Preparation of Silylated Pyrrolidones Through Palladium-Catalyzed Cyclizations.

✍ Scribed by Serge Thorimbert; Giuliano Giambastiani; Claude Commandeur; Maxime Vitale; Giovanni Poli; Max Malacria

Publisher
John Wiley and Sons
Year
2003
Weight
82 KB
Volume
34
Category
Article
ISSN
0931-7597

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Transition-metal-catalyzed cyclization of dienes, diynes, and enynes has received considerable attention in recent years. [1] In contrast, cyclization of this class of compounds through functionalization of a CΓ€H bond of an aromatic ring has scarcely been investigated. We anticipated that tandem cyc