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Diastereoselective inter- and Intramolecular Cycloaddition reactions of Nitrilimines derived from sugars

✍ Scribed by Pál Herczegh; Attila Agócs; Attila Bényei; Gyula Batta


Book ID
108403076
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
152 KB
Volume
34
Category
Article
ISSN
0144-8617

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✍ Pál Herczegh; Zsély Martina; Szilágyi László; Dinya Zoltán; Bognár Rezső 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 431 KB

Abstract4 A mixture of tetrachiral deca-1,7E,9-triene 2 and its 72 isomer 2 was prepared from D-glucose by the use of two Wittig olefination reactions. When 5 or 6 were subjected to intramolecular Diels-Alder reaction un'-er Thermal conditions the same, cis-fused octahydronaphtalene enantiomer 9 was