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Diastereoselective Cycloalkylation of Phosphoryl and Thiophosphoryl Acetonitriles by α,ψ-Dihalogenalkanes under Phase Transfer Catalysis Conditions.

✍ Scribed by I. L. Odinets; N. M. Vinogradova; K. A. Lyssenko; P. V. Petrovskii; T. A. Mastryukova; G-V. Roeschenthaler

Publisher
John Wiley and Sons
Year
2006
Weight
28 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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📜 SIMILAR VOLUMES

Diastereoselective cycloalkylation of ph
Diastereoselective cycloalkylation of phosphoryl and thiophosphoryl acetonitriles by α,ψ-dihalogenalkanes under phase transfer catalysis conditions
✍ I. L. Odinets; N. M. Vinogradova; K. A. Lyssenko; P. V. Petrovskii; T. A. Mastry 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 140 KB

## Cycloalkylation of phosphoryl and thio- phosphoryl acetonitriles 2 by ␣, -dihalogenalkanes was found to proceed diastereoselectively under phase transfer catalytic conditions yielding 1-(phosphoryl)-2-methyl-cycloalkane carbonitriles as trans-isomers with identical configuration of asymmetric cyc