Diastereoselective cyclization of 6-octen-1-als with rhodium(I)-complex

✍ Scribed by Kazuhisa Funakoshi; Nagako Togo; Kiyoshi Sakai

• Book ID: 104232812
• Publisher: Elsevier Science
• Year: 1989
• Tongue: French
• Weight: 229 KB
• Volume: 30
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)80369-5

✦ Synopsis

Rhodium(I)-catalyzed cyclization of 6-octen-l-al with chiral protecting group ((4R,GR)-dimethyl-1,3-dioxane) at the C3 afforded diastereoselectively the trans-cgclohexanol.

Previously, we reported on Rh(I)-catalyzed stereoselective cyclization 1)