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Diastereoselective construction of chiral building blocks for the synthesis of indole alkaloids using an intramolecular Heck reaction

✍ Scribed by Yuri Murakami; Masahiro Yoshida; Kozo Shishido

Publisher: Elsevier Science
Year: 2009
Tongue: French
Weight: 494 KB
Volume: 50
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2008.12.105

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✦ Synopsis

Highly diastereoselective construction of the chiral building blocks, with an allylic quaternary carbon stereogenic center, for the synthesis of indole alkaloids has been accomplished by employing a 1,4-chirality transfer via the intramolecular Heck reaction.

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