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Diastereoselective Allylation of Planar Chiral Substituted Ferrocenecarboxaldehyde: An Efficient Entry to Chiral Ferrocenyl Ligands.

✍ Scribed by Hao Li; Hin-Soon Cheng; Ai-Hua Seow; Teck-Peng Loh


Publisher
John Wiley and Sons
Year
2007
Weight
24 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Allylation and propargylation of chiral
✍ Carlos Cativiela; María D. Díaz-De-Villegas; José A. Gálvez; Eva Ronco 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 160 KB

## Abstract α‐Methyllysine and 2‐amino‐2‐methylundecanoic acid, two α,α‐disubstituted unnatural glycines, were synthesized using highly diastereoselective allylation or propargylation of chiral (1__S__,2__R__,4__R__)‐10‐dicyclohexylsulfamoylisobornyl 2‐cyanopropanoate as the key step to introduce t