Diastereoselective allylation of chiral imines. Novel application of allylcopper reagents to the enantioselective synthesis of homoallyl amines

✍ Scribed by Allaye Bocoum; Carla Boga; Diego Savoia; Achille Umani-Ronchi

• Book ID: 104216105
• Publisher: Elsevier Science
• Year: 1991
• Tongue: French
• Weight: 239 KB
• Volume: 32
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)79669-9

✦ Synopsis

The addition of allylcopper reagents to imines derived from S-valine occurs with excellent diastereoselectivity (e.e. 98 %).