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Diastereoselective aldol reactions of 2,6-dimethylcyclohexenone lithium enolate

✍ Scribed by Alfonso Fernández Mateos; Gustavo Pascual Coca; JoséJ. Pérez Alonso; Rosa Rubio González; Carolina Tapia Hernández

Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
176 KB
Volume
36
Category
Article
ISSN
0040-4039

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✍ Roy L. Beddoes; Mark L. Lewis; Peter Quayle; Yuekun Zhao; Michael Attwood 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 281 KB

The al&l reactions and subsequent &znsrnetallarion of ~skannylpropionates is described. We recently reported' that the lithium enolate (2) undergoes clean alkylation reactions generating the stannanes (3) with high levels of asymmeaic induction (d.s. > 99:5). The stannanes (3) serve as useful inter