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Diastereoselective addition of metalated isoindolin-1-ones to aldehydes. Stereoselective preparation of (E)-3-arylideneisoindolin-1-ones

✍ Scribed by Axel Couture; Eric Deniau; Pierre Grandclaudon; Christophe Hoarau; Véronique Rys


Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
125 KB
Volume
43
Category
Article
ISSN
0040-4039

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Diastereoselective Addition of Radicals
✍ Heiner Graalfs; Roland Fröhlich; Christian Wolff; Jochen Mattay 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 535 KB

Intermolecular addition of radicals to the 1,3-dioxin-4-ones an unsaturated side chain were attacked by radicals at the terminal double bond. In the case of irradiation of 32b in 1,3-1a,b and 2a,b with (-)-menthone incorporated as chiral auxiliary in 2-position were investigated. Photochemically dio