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Diastereoselective Addition of 2 H -2-Oxo-1,4,2-oxazaphosphinanes to Aldehydes and Imines

✍ Scribed by Pirat, Jean-Luc; Monbrun, Jérôme; Virieux, David; Volle, Jean-Noël; Tillard, Monique; Cristau, Henri-Jean

Book ID
126402277
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
217 KB
Volume
70
Category
Article
ISSN
0022-3263

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A convenient synthesis of 2-alkoxy-2-oxo
A convenient synthesis of 2-alkoxy-2-oxo-1,4,2-oxazaphosphinanes
✍ Bin Wang; Zhiwei Miao; You Huang; Ruyu Chen 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 129 KB 👁 1 views

A study on the synthesis of the novel cyclic ␣-aminophosphonates and 2-alkoxy-2oxo-1,4,2-oxazaphosphinanes 4a-r has been carried out. The title compounds were obtained in good yields by one-pot procedure using o-aminophenol, alkyl dichlorophosphinite, and ketones or benzaldehyde. One of their geomet