✦ LIBER ✦

Diastereoselective [2,3] Wittig rearrangement of carbohydrate-derived tertiary allylic ethers. 1. Synthesis of the C11-C18 subunit of herbimycin a from D-glucose.

✍ Scribed by Jill E. Eshelman; Janet L. Epps; James Kallmerten

Publisher: Elsevier Science
Year: 1993
Tongue: French
Weight: 289 KB
Volume: 34
Category: Article
ISSN: 0040-4039
DOI: 10.1016/0040-4039(93)89002-8

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Diastereoselective [2,3] Wittig rearrang

Diastereoselective [2,3] Wittig rearrangement of carbohydrate-derived tertiary allylic ethers. 2. Synthesis of an advanced rapamycin intermediate from D-glucose.

✍ Ny Sin; James Kallmerten 📂 Article 📅 1993 🏛 Elsevier Science 🌐 French ⚖ 276 KB

The [2,3] Wittig rearrangement of tertia

The [2,3] Wittig rearrangement of tertiary allylic ethers. Application to the synthesis of the C12C25 subunit of zincophorin

✍ Michael Balestra; Mark D Wittman; James Kallmerten 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 253 KB

Ketone 4 representing the C12-C25 subunit of the ionophore antibiotic zincophorin, has been prepared by a sequence incorporating the [2,3] Wittig rearrangement of a tertiary allylic ether and subsequent lactonization via intramolecular, acid-catalyzed SN' addition to an allylic ether.