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Diastereoselection in the reactions of thioallylic anions with benzaldehyde

โœ Scribed by Toshio Hayashi; Nobuo Fujitaka; Takeshi Oishi; Tatsuo Takeshima


Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
257 KB
Volume
21
Category
Article
ISSN
0040-4039

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REACTIONS OF LITHIUM WITH BENZALDEHYDE I
โœ N. S. Nudelman; Sara Mendiara ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 157 KB ๐Ÿ‘ 2 views

Benzaldehyde in THF reacts with lithium metal to give the expected reduction product, benzyl alcohol, plus benzoin and benzyl as minor products. The kinetics of the overall reaction as well as the partial rate coefficients of the several steps have been determined under various reaction conditions.