✦ LIBER ✦
Diastereomeric non-equivalence of (−)-ω-camphanic esters of chiral secondary alcohols in 13C NMR spectroscopy
✍ Scribed by Janusz Jurczak; Andrzej Konowal; Zbigniew Krawczyk; Andrzej Ejchart
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 271 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The diastereomeric differences (Δδ) were measured by ^13^C NMR spectroscopy for a series of 11 (−)‐ω‐camphanic esters of secondary alcohols of known absolute configuration. This method cannot be used for the determination of the absolute configuration, but it can be applied to the estimation of the enantiomeric purity of chiral alcohols.