Diastereofacially Selective Enolate Claisen Rearrangements of (4-7-. eta.4-(1-Acyloxy-2,4,6-octatrienyl))tricarbonyliron Complexes. -Under the optimized conditions shown, the esters (I) and (II) rearrange with very high diastereofacial selectivity. C-C bond formation occurs anti to the Fe(CO)3 grou
✦ LIBER ✦
Diastereofacially selective enolate Claisen rearrangements of [4−7-η4-(1-acyloxy-2,4,6-octatrienyl)]tricarbonyliron complexes
✍ Scribed by William R. Roush; Andrea B. Works
- Book ID
- 104256096
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 243 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The enolate Claisen rearrangements of l-4 exhibit very high diastereofacial selectivity with the developing C-C bond forming anti to the -Fe( CO ) 3 substituent.
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