𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Diastereo- and Enantioselective Synthesis of 1,2,3-Substituted Cyclopropanes with Zinc Carbenoids

✍ Scribed by Prof. André B. Charette; Jacinthe Lemay


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
410 KB
Volume
36
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Highly Diastereo- and Enantioselective S
✍ Dieter Enders; Thomas Hundertmark; Cornelia Lampe; Udo Jegelka; Ilse Scharfbilli 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 229 KB 👁 1 views

An efficient asymmetric synthesis of protected anti-1,3-diols by reduction of the ketones 2 and a variant of the Barton-McCombie deoxygenation. The new method allows the 5 (de Ն 98%, ee = 92-98%) from 2,2-dimethyl-1,3-dioxan-5one SAMP hydrazone 1 is described. The key steps are the synthesis of acet