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Diastereo- and Enantioselective Gold(I)-Catalyzed Intermolecular Tandem Cyclization/[3+3]Cycloadditions of 2-(1-Alkynyl)-2-alken-1-ones with Nitrones

✍ Scribed by Feng Liu; Deyun Qian; Lei Li; Xiaoli Zhao; Junliang Zhang


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
373 KB
Volume
122
Category
Article
ISSN
0044-8249

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## Abstract A highly efficient method has been developed for the one‐pot synthesis of multi‐ring heterocyclic compounds such as pyrrolo‐/pyrido[2,1‐__b__]benzo[__d__][1,3]oxazin‐1‐ones from __o__‐aminobenzyl alcohols __via__ a gold(I)‐catalyzed tandem coupling/cyclization reaction. Significantly, t