Diaryliodonium Salts. XIV. Reactions of Organometallic Compounds with Iodosobenzene Dichlorides and with Iodonium Salts 1,2
β Scribed by Beringer, F. Marshall; Dehn, Joseph W.; Winicov, Murray
- Book ID
- 126241199
- Publisher
- American Chemical Society
- Year
- 1960
- Tongue
- English
- Weight
- 685 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0002-7863
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The Stille coupling of (Z)-1,2-bis(trimethylstannyl)ethenes with hypervalent iodonium salts (1 equiv) proceeded stereospecifically in the presence of PdCI\_, (5 mol %) in DMF at room temperature to afford partially substituted (Z)-vinylstannanes under mild conditions. Alternatively, the use of 2 equ
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