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Diaquatetrakis(1,3-di-4-pyridylpropane-κN)manganese(II) bis(hexafluoridophosphate) monohydrate

✍ Scribed by Zheng, Xianfu ;Niu, Caoyuan ;Wan, Xinsheng ;Kou, Chunhong

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
816 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title mononuclear Mn^II^ complex, Mn(C~13~H~14~N~2~)~4~(H~2~O)~2~~2~·H~2~O, is isostructural with the previously reported Zn^II^ complex. The metal center is coordinated by four monodentate 1,3-di-4-pyridylpropane (__L__1) ligands and two water molecules. One __L__1 ligand is affected by disorder of two propane C atoms, which are distributed over two positions, with occupancies 0.771 (8)/0.229 (8). The asymmetric unit is completed by one solvent water molecule and two PF~6~
^−^ anions, both disordered over two positions, with occupancies for F atoms of 0.621 (10)/0.379 (10) for one anion and 0.69 (2)/0.31 (2) for the other. Uncoordinated N atoms of pyridyl groups belonging to __L__1 and water molecules are involved in hydrogen bonds, with D...A separations ranging from 1.85 (4) to 2.07 (4) Å and D—H...A angles from 169 (3) to 174 (4)°.

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