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Diaquahydrogenium hexachloroantimonate (V). Observed and calculated infrared spectra

✍ Scribed by R. Janoschek; R. Ortwein; A. Schmidt

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
236 KB
Volume
37
Category
Article
ISSN
0009-2614

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✦ Synopsis

The diaquahydrogenium hes;rchIoronntimonte(V) H50$SbC!l~(I) snd D,O~SbCl~(II) were prepared by the reaction of SbCl~*2Hz0 and SbCIS. 2DzO with HCI or DC1 respectively. The infrrued r;pectra were assigned. In addition nb initio alculations were performed on the system HsOi, for which frequencies and IR absorbanccs of three mutually perpcndicular modes of the H-bonded proton and D-bonded deuteron were crllcuhted.

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## Abstract The ultraviolet circular dichroism (CD) of oriented DNA and RNA molecules is calculated by an extension of Johnson and Tinoco's theory [(1969) __Biopolymers__ **7**, 727–749] for unoriented molecules. The calculations are carried out for molecular models of A‐DNA, B‐DNA, planar B‐DNA, C