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Diaquabis(1 H -imidazole-4-carboxylato-κ 2N 3 , O 4 )manganese(II)

✍ Scribed by Xiong, Zhi-Yong; Li, Lin; Zhao, Xiang-Jie; Chen, Hai-Ming

Book ID
121660974
Publisher
International Union of Crystallography
Year
2013
Tongue
English
Weight
409 KB
Volume
69
Category
Article
ISSN
1600-5368

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Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-
Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-imidazole-κN3)manganese(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 135 KB

The Mn atom in the title compound, [Mn(C 8 H 5 O 3 ) 2 -(C 3 H 4 N 2 ) 2 (H 2 O) 2 ], is datively linked to the imidazole heterocycles and water molecules, and covalently linked to the substituted benzoate groups in an all-trans octahedral geometry; the Mn atom lies on a center of inversion.

catena-Poly[[aqua(pyrazine-2-carboxylato
catena-Poly[[aqua(pyrazine-2-carboxylato-κ2N1,O)manganese(II)]-μ-pyrazine-2-carboxylato-κ3N1,O:N4]
✍ Gao, Yu-Xiang ;Wang, Li-Bin ;Niu, Yan-Ling ;Hao, Lu-Jiang 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 759 KB

The title compound, [Mn(C 5 H 3 N 2 O 2 ) 2 (H 2 O)] n , prepared by hydrothermal synthesis, is isostructural with its Fe II , Co II , Ni II and Cu II analogues. The asymmetric unit contains two bidendate pyrazine-2-carboxylate anions coordinated to Mn II in the equatorial plane through one N and on