Diaqua(7,l5-dihydro-7,9,13,15-tetramethylpyrido[2',1',6':12,13,14][1,2,4,7,9,10,13]heptaazacyclopentadeca[3,4,5,6,7,8-aklmn][1,10]phenanthroline)cobalt(II) bis(tetrafluoroborate) [Co(H2O)2(tdmmb)][BF4]2
β Scribed by Hanton, L. R. ;Raithby, P. R.
- Book ID
- 114526995
- Publisher
- International Union of Crystallography
- Year
- 1980
- Weight
- 341 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0567-7408
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## Abstract The molecular structures of the title compounds 3 and 5 were investigated by NMR and Xβray structural methods. The NMR results suggest two equivalent halves for both molecules. The Xβray study shows an approximate mirror plane for 3 and an approximate twofold axis for a significant port
The Mn^V^ complex in the title compound, (C~8~H~20~N)[Mn(C~21~H~26~N~4~O~4~)O], is interesting as it has been suggested that Mn^V^ oxospecies are intermediates both in epoxidation of alkenes and in water oxidation in PSII, __i.e.__ photosystem II, the protein found in oxygenic photosynthetic organis