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Dianionic complexes with hexacoordinate silicon(IV) or germanium(IV) and three bidentate ligands of the salicylato(2–) type: Syntheses and structural characterization in the solid state and in solution

✍ Scribed by Oliver Seiler; Christian Burschka; Martin Penka; Reinhold Tacke

Book ID: 111611538
Publisher: Springer
Year: 2002
Tongue: English
Weight: 185 KB
Volume: 1
Category: Article
ISSN: 1569-0660
DOI: 10.1023/b:silc.0000025573.50788.6c

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## Abstract Two neutral complexes [(L~6~^3^4M)Fe~2~Cl~4~]·2H~2~O·2CHCl~3~ (1) and [(L~6~^3^4M)Mn~2~Cl~4~]·CH~3~CN (2) have been synthesized {L~6~^3^4M = __N__,__N__,__N′__,__N′__‐tetrakis[(6‐methyl‐2‐pyridyl)methyl]propane‐1,3‐diamine} and their molecular structures established by X‐ray crystallogr