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Dianilinium tetradeca­chloro­hexamolybdate dihydrate, (PhNH3)2[(Mo6Cl8)Cl6]·2H2O

✍ Scribed by Flemström, Andreas

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
292 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, (C 6 H 8 N) 2 [(Mo 6 Cl 8 )Cl 6 ]Á2H 2 O, the anilinium salt of an Mo II chloride cluster, shows a rigid and stable hydrogen-bonded network. The chloromolybdate cluster dianion occupies a special position on a twofold axis.

📜 SIMILAR VOLUMES

[Yb(H2O)8] [Cd3Cl9(H2O)]×6H2O.
[Yb(H2O)8] [Cd3Cl9(H2O)]×6H2O.
✍ Samia Yahyaoui; Rached Ben Hassen; Bruno Donnadieu; Jean-Claude Daran; Abdelhami 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 56 KB 👁 1 views
Synthesis, Structures and Properties of
Synthesis, Structures and Properties of Cluster Complexes [H3O(Ph3PO)3]2[Mo6Cl14] and [H(Ph3PO)2]2[Re6S6Br8]
✍ Zhyldyz S. Kozhomuratova; Yuri V. Mironov; Michael A. Shestopalov; Irina V. Dreb 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 218 KB

## Abstract New cluster compounds [H~3~O(Ph~3~PO)~3~]~2~[Mo~6~Cl~14~] (I) and [H(Ph~3~PO)~2~]~2~[Re~6~S~6~Br~8~] (II) have been prepared by the reaction of a acetonitrile solution of triphenylphosphane oxide Ph~3~PO with octahedral cluster complexes of molybdenum (H~3~O)~2~Mo~6~Cl~14~·6H~2~O and rh

Synthesis, Structure, and Decomposition
Synthesis, Structure, and Decomposition of (NH4)2[Mo6Cl14] · H2O
✍ Andreas Nägele; Katharina Gibson; Abdessadek Lachgar; H.-Jürgen Meyer 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 106 KB 👁 1 views

NH 4 ) 2 [Mo 6 Cl 14 ] ´H2 O (1) was prepared from reactions of MoCl 2 in ethanol with aqueous NH 4 Cl solution. It crystallizes in the monoclinic space group I2/a (no. 15), Z = 4 with a = 912.3(1), b = 1491.2(2), c = 1724.8(2) pm, b = 92.25(1)°; R1 = 0.023 (based on F values) and wR2 = 0.059 (based