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Diammonium cyclopropane-1,1-dicarboxylate

✍ Scribed by Bréhin, P. ;Kozelka, J. ;Bois, C.

Book ID
114509646
Publisher
International Union of Crystallography
Year
1992
Tongue
English
Weight
322 KB
Volume
48
Category
Article
ISSN
0108-2701

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Pd(O) promoted rearrangement of 2-(1,3-b
Pd(O) promoted rearrangement of 2-(1,3-butadienyl)cyclopropane- 1,1-dicarboxylate esters to 2-alkenyl-3-cyclopentene-1,1-dicarboxylate esters
✍ Yoshitomi Morizawa; Koichiro Oshima; Hitosi Nozaki 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 233 KB

The title dienylcyclopropanes smoothly rearrange to five-membered rings in the presence of a Pd(0) catalyst under mild conditions. Although the vinylcyclopropane-cyclopentene rearrangement' has attracted mechanistic interest, the synthetic application has been limited because of the high temperature