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Dialkyltin oxide mediated addition of trimethylsilyl azide to nitriles. A novel preparation of 5-substituted tetrazols

✍ Scribed by Wittenberger, Steven J.; Donner, B. Gregory


Book ID
120060045
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
363 KB
Volume
58
Category
Article
ISSN
0022-3263

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tris(2-perfluorohexylethyl)tin azide: A
✍ Dennis P. Curran; Sabine Hadida; Sun-Young Kim πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 594 KB

The synthesis of a new fluorous tin azide, (C6FI3CH2CH2)3SnN 3, is reported and this reagent is used to make tetrazoles in both traditional and phaseswitching modes. In the traditional mode, the tin azide is reacted with nitriles followed by HCl cleavage to provide the tetrazoles and the fluorous ti