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Diacetone glucose-derived dienes in Diels-Alder reactions. Products and transformations

✍ Scribed by Sun, King Mo; Giuliano, Robert M.; Fraser-Reid, Bert

Book ID
115491878
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
992 KB
Volume
50
Category
Article
ISSN
0022-3263

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Oxidation with barium manganate of the enol of dicyanobenzoquinone of meso-17 yields (E)-7b and an isomer (77:23) which was assigned structure (Z)-7b on the tetraacetylethane (10) affords tetraacetylethylene (7a) in good yield. Treatment of the 1,3-diketones 15a and b with basis of spectroscopic evi