The relations between the stochastic and transition-state theories are reconsidered on the basis of a harmonic oscillator model. It is shown from the physical point of view that both theories are not equivalent.
Diabatic transition state theory and the concept of temperature
โ Scribed by G. Ludwig Hofacker; R.D. Levine
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 539 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
A modified transition state theory, appropriate for direct reactions, which incorporates dynamic constraints and can account for popuhtion inversion, is presented. it is shown that the distribution of vibntionni states can be czaracterized by ;i lagrangian parameter that can be interpreted ns tempemture.
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